The National Personnel Records Center (NPRC) has provided the following website for veterans to gain access to their DD-214s

Online: http://vetrecs.archives.gov/

This may be particularly helpful when a veteran needs a copy of his DD-214
for employment purposes. NPRC is working to make it easier for veterans
with computers and Internet access to obtain copies of documents from  their military files.

Military veterans and the next of kin of deceased former military members may now use a new online military personnel records system to request
documents. Other individuals with a need for documents must still complete the Standard Form 180, which can be downloaded from the online web site.
Because the requester will be asked to supply all information essential for NPRC to process the request, delays that normally occur when NPRC has to ask veterans for additional information will be minimized. The new web-based application was designed to provide better service on these
pressing time.
Please pass this information on to former military personnel you may know and their dependents

This information provided by member Walt Ptaskiewicz